Recent developments in recyclable copper catalyst systems for C-N bond forming cross-coupling reactions using aryl halides and arylboronic acids

Kantam, M, Reddy, C, Srinivas, P and Bhargava, S 2013, 'Recent developments in recyclable copper catalyst systems for C-N bond forming cross-coupling reactions using aryl halides and arylboronic acids' in M. Taillefer, D. Ma (ed.) Topics in Organometallic Chemistry, Springer-Verlag, Germany, pp. 119-171.


Document type: Book Chapter
Collection: Book Chapters

Title Recent developments in recyclable copper catalyst systems for C-N bond forming cross-coupling reactions using aryl halides and arylboronic acids
Author(s) Kantam, M
Reddy, C
Srinivas, P
Bhargava, S
Year 2013
Title of book Topics in Organometallic Chemistry
Publisher Springer-Verlag
Place of publication Germany
Editor(s) M. Taillefer, D. Ma
Volume number 46
Start page 119
End page 171
Subjects Catalysis and Mechanisms of Reactions
Summary This review covers the recent recyclable protocols for the C-N bond forming reactions between aromatic, heterocyclic and aliphatic amines such as imidazoles, benzimidazoles, benzylamines, piperidine, pyrrole, imides, anilines, hexyl, cyclohexyl amines, and amides as coupling partners with aryl iodides, bromides, chlorides, and arylboronic acids employing copper-mediated systems. The physical properties and characterization of the catalysts and their use in organic synthesis will be outlined. Most importantly, these recyclable versions developed by many groups in the recent years are potential candidates for commercial exploitation. The effect of additives, solvents, temperature, base, the nature of aryl halides on reactivity, and recycle studies of the heterogeneous catalysts are included in this review. We believe that this information is beneficial for the people who are doing similar studies in this field. Catalyst optimization is of critical importance to catalyst development, thus the information we have included in this review contains very valuable information for the newcomers to the field. To our knowledge this is the first review that covers the title chemistry.
Copyright notice © Springer-Verlag Berlin Heidelberg 2013
Keyword(s) Aryl halides
C-N bond formation
Copper catalyst
Cross-Coupling
Heterocycles
Heterogeneous
Reusable catalysts
DOI - identifier 10.1007/3418_2012_58
ISBN 9783642405457
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Created: Wed, 14 Jan 2015, 13:53:00 EST by Catalyst Administrator
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