Nanocrystalline magnesium oxide stabilized palladium(0): an efficient reusable catalyst for room temperature selective aerobic oxidation of alcohols

Layek, K, Maheswaran, H, Arundhathi, R, Lakshmi Kantam, M and Bhargava, S 2011, 'Nanocrystalline magnesium oxide stabilized palladium(0): an efficient reusable catalyst for room temperature selective aerobic oxidation of alcohols', Advanced Synthesis & Catalysis, vol. 353, no. 4, pp. 606-616.


Document type: Journal Article
Collection: Journal Articles

Title Nanocrystalline magnesium oxide stabilized palladium(0): an efficient reusable catalyst for room temperature selective aerobic oxidation of alcohols
Author(s) Layek, K
Maheswaran, H
Arundhathi, R
Lakshmi Kantam, M
Bhargava, S
Year 2011
Journal name Advanced Synthesis & Catalysis
Volume number 353
Issue number 4
Start page 606
End page 616
Total pages 11
Publisher Wiley - V C H Verlag GmbH & Co. KgaA
Abstract Nanocrystalline magnesium oxide-stabilized palladium(0) [NAP-Mg-Pd(0)], as an efficient catalytic system has been employed for the selective oxidation of alcohols using atmospheric oxygen as a green oxidant at room temperature. Various alcohols could be transformed into their corresponding aldehydes or ketones in good to excellent yields using a set of optimal conditions. NanoActive Magnesium Oxide Plus, [NAP-MgO] with its three-dimensional structure and well-defined shape acts as an excellent support for well dispersed palladium(0) nanoparticles. This catalyst can be recovered and reused for several cycles without any significant loss of catalytic activity.
Subject Chemical Engineering not elsewhere classified
Materials Engineering not elsewhere classified
Keyword(s) aerobic oxidation
alcohols
aldehydes
catalyst recycling
heterogeneous catalysis
DOI - identifier 10.1002/adsc.201000591
Copyright notice © 2011 Wiley VHC Verlag GmbH & Co KGaA, Weinheim
ISSN 1615-4150
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