Nanocrystalline magnesium oxide-stabilized palladium(0): the Heck reaction of heteroaryl bromides in the absence of additional ligands and base

Kantam, M, Reddy, P, Srinivas, P, Venugopal, A, Bhargava, S and Nishina, Y 2013, 'Nanocrystalline magnesium oxide-stabilized palladium(0): the Heck reaction of heteroaryl bromides in the absence of additional ligands and base', Catalysis Science and Technology, vol. 3, no. 10, pp. 2550-2554.


Document type: Journal Article
Collection: Journal Articles

Title Nanocrystalline magnesium oxide-stabilized palladium(0): the Heck reaction of heteroaryl bromides in the absence of additional ligands and base
Author(s) Kantam, M
Reddy, P
Srinivas, P
Venugopal, A
Bhargava, S
Nishina, Y
Year 2013
Journal name Catalysis Science and Technology
Volume number 3
Issue number 10
Start page 2550
End page 2554
Total pages 5
Publisher RSC Publications
Abstract An efficient and user-friendly protocol has been realized for the Heck reaction of heteroaryl bromides by using a reusable nanocrystalline magnesium oxide-stabilized palladium(0) catalyst without the aid of additional ligands and base. Dimethylamine generated under in situ conditions by the decomposition of DMF serves as the base in this reaction. The catalyst was reused with consistent activity up to four cycles.
DOI - identifier 10.1039/c3cy00404j
Copyright notice This journal is © The Royal Society of Chemistry 2013
ISSN 2044-4753
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