Impact of Hydrophobic Organohybrid Silicas on the Stability of Ni2P Catalyst Phase in the Hydrodeoxygenation of Biophenols

Dierks, M, Cao, Z, Manayil, J, Akilavasan, J, Wilson, K, Schuth, F and Rinaldi, R 2018, 'Impact of Hydrophobic Organohybrid Silicas on the Stability of Ni2P Catalyst Phase in the Hydrodeoxygenation of Biophenols', ChemCatChem, vol. 10, no. 10, pp. 2219-2231.


Document type: Journal Article
Collection: Journal Articles

Title Impact of Hydrophobic Organohybrid Silicas on the Stability of Ni2P Catalyst Phase in the Hydrodeoxygenation of Biophenols
Author(s) Dierks, M
Cao, Z
Manayil, J
Akilavasan, J
Wilson, K
Schuth, F
Rinaldi, R
Year 2018
Journal name ChemCatChem
Volume number 10
Issue number 10
Start page 2219
End page 2231
Total pages 13
Publisher Wiley
Abstract Hydrodeoxygenation (HDO) of lignocellulose-derived pyrolysis oils offers an option to produce fuel substitutes. However, catalyst deactivation and stability constitute a significant issue. Herein, the dependence of stability and activity of Ni2P/SiO2 HDO catalysts on the support surface polarity is addressed in detail. The support surface polarity was adjusted by copolymerizing tetraethyl orthosilicate (TEOS) with different types and amounts of organosilanes by a solgel process in the presence of nickel nitrate and citric acid. After thermal treatment under an inert atmosphere, Ni/SiO2 precursors were formed. They were converted into Ni2P/SiO2 catalysts by using NaH2PO2 as a PH3 source. The catalyst surface polarity was characterized by inverse gas chromatography measurements of the free energy of methanol adsorption, and specific and dispersive surface energies derived from polar and nonpolar probe molecule adsorption. The correlation between catalyst performance and support surface polarity indicates that, to prevent deactivation of the catalyst by water under reaction conditions, the affinity of the support towards polar substances must be decreased below a threshold value.
Subject Catalysis and Mechanisms of Reactions
Keyword(s) catalyst deactivation
hydrodeoxygenation
organosilanes
support surface polarity
tetraethyl orthosilicate
DOI - identifier 10.1002/cctc.201702001
Copyright notice © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
ISSN 1867-3880
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