Facile Fabrication of Polymerizable Ionic Liquid Based-Gel Beads via Thiol-ene Chemistry

Taghavikish, M, Subianto, S, Dutta, N and Choudhury, N 2015, 'Facile Fabrication of Polymerizable Ionic Liquid Based-Gel Beads via Thiol-ene Chemistry', ACS Applied Materials and Interfaces, vol. 7, no. 31, pp. 17298-17306.


Document type: Journal Article
Collection: Journal Articles

Title Facile Fabrication of Polymerizable Ionic Liquid Based-Gel Beads via Thiol-ene Chemistry
Author(s) Taghavikish, M
Subianto, S
Dutta, N
Choudhury, N
Year 2015
Journal name ACS Applied Materials and Interfaces
Volume number 7
Issue number 31
Start page 17298
End page 17306
Total pages 9
Publisher American Chemical Society
Abstract Multipurpose gel beads prepared from natural or synthetic polymers have received significant attention in various applications such as drug delivery, coatings, and electrolytes because of their versatility and unique performance as micro-and nanocontainers.1 However, comparatively little work has been done on poly(ionic liquid)-based materials despite their unique ionic characteristics. Thus, in this contribution we report the facile preparation of polymerizable ionic liquid-based gel beads using thiol-ene click chemistry. This novel system incorporates pentaerythritol tetra (3-mercaptopropionate) (PETKMP) and 1,4-di(vinylimidazolium) butane bisbromide in a thiol-ene-based photopolymerization to fabricate the gel beads. Their chemical structure, thermal and mechanical properties have been investigated using Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and dynamic mechanical analysis (DMA). The gel beads possess low T<inf>g</inf> and their ionic functionalities attribute self-healing properties and their ability to uptake small molecules or organic compounds offers their potential use as pH sensing material and macrocontainers.
Subject Chemical Engineering not elsewhere classified
Functional Materials
Nanomaterials
Keyword(s) gel beads
pH sensing material
polymerizable ionic liquid
self-healing
thiol-ene chemistry
DOI - identifier 10.1021/acsami.5b04405
Copyright notice © 2015 American Chemical Society.
ISSN 1944-8244
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