Ion-selective carbon nanotube electrodes in capacitive deionisation

Yang, J, Zou, L and Choudhury, N 2013, 'Ion-selective carbon nanotube electrodes in capacitive deionisation', Electrochimica Acta, vol. 91, pp. 11-19.

Document type: Journal Article
Collection: Journal Articles

Title Ion-selective carbon nanotube electrodes in capacitive deionisation
Author(s) Yang, J
Zou, L
Choudhury, N
Year 2013
Journal name Electrochimica Acta
Volume number 91
Start page 11
End page 19
Total pages 9
Publisher Elsevier
Abstract In the capacitive deionisation (CDI) process, counter-ions in the solution are adsorbed on the electrodes, and co-ions are expelled from the electrodes. This so-called co-ion effect hinders desalting performance of the electrodes. To overcome this problem, we directly grafted the carbon nanotubes (CNTs) with sulfonic and amine functional groups, using an aryl diazonium salt solution and 3-aminopropyltriethoxysilane (APTES). These grafted groups can act as ion-selective functional coatings similar to the ion-exchange membranes without adding too much electrical resistance. Also, they can increase the hydrophilicity and wettability of the CNTs' surface. The structure and electrochemical properties of functionalised CNTs are tested for CDI. Four CDI cells were assembled used different combination of the sulfonated and aminated and unmodified CNTs. Improved CDI performance was found when the modified samples were used in aspect of salt-removal capacity and/or electrosorption rate. In summary, the functionalised-CNTs electrodes enhanced the salt-removing performance in the CDI process.
Subject Physical Chemistry of Materials
Composite and Hybrid Materials
Keyword(s) Capacitive deionisation (CDI)
Ion selectivity
Surface functional groups
DOI - identifier 10.1016/j.electacta.2012.12.089
Copyright notice © 2012 Elsevier Ltd. All rights reserved.
ISSN 0013-4686
Version Filter Type
Citation counts: TR Web of Science Citation Count  Cited 63 times in Thomson Reuters Web of Science Article | Citations
Scopus Citation Count Cited 0 times in Scopus Article
Altmetric details:
Access Statistics: 34 Abstract Views  -  Detailed Statistics
Created: Thu, 31 Jan 2019, 11:26:00 EST by Catalyst Administrator
© 2014 RMIT Research Repository • Powered by Fez SoftwareContact us