A Redox Switchable Dihydrobenzo[b]pyrazine Push-Pull System

Maniam, S, Higginbotham, H, Guo, S, Bell, T, Izgorodina, E and Langford, S 2014, 'A Redox Switchable Dihydrobenzo[b]pyrazine Push-Pull System', Asian Journal of Organic Chemistry, vol. 3, no. 5, pp. 619-623.

Document type: Journal Article
Collection: Journal Articles

Title A Redox Switchable Dihydrobenzo[b]pyrazine Push-Pull System
Author(s) Maniam, S
Higginbotham, H
Guo, S
Bell, T
Izgorodina, E
Langford, S
Year 2014
Journal name Asian Journal of Organic Chemistry
Volume number 3
Issue number 5
Start page 619
End page 623
Total pages 5
Publisher Wiley
Abstract The synthesis and spectroscopic properties of a dissymmetrically core-extended naphthalene diimides derived from o-phenylenediamine and cyanoethene dithiolate were explored. The push-pull nature of the peripheral substituents allows these naphthalene diimide dyes and their progenitors to display interesting photophysical and electrochemical properties, with the target system acting as a highly reversible and quantitative molecular switch with clear absorption and emission readouts based on chemical oxidation and reduction processes.
Subject Organic Chemical Synthesis
Sensory Systems
Keyword(s) Dyes
Naphthalene diimides
Push-pull system
Redox switch
DOI - identifier 10.1002/ajoc.201402015
Copyright notice © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
ISSN 2193-5807
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