A Redox Switchable Dihydrobenzo[b]pyrazine Push-Pull System

Maniam, S, Higginbotham, H, Guo, S, Bell, T, Izgorodina, E and Langford, S 2014, 'A Redox Switchable Dihydrobenzo[b]pyrazine Push-Pull System', Asian Journal of Organic Chemistry, vol. 3, no. 5, pp. 619-623.


Document type: Journal Article
Collection: Journal Articles

Title A Redox Switchable Dihydrobenzo[b]pyrazine Push-Pull System
Author(s) Maniam, S
Higginbotham, H
Guo, S
Bell, T
Izgorodina, E
Langford, S
Year 2014
Journal name Asian Journal of Organic Chemistry
Volume number 3
Issue number 5
Start page 619
End page 623
Total pages 5
Publisher Wiley
Abstract The synthesis and spectroscopic properties of a dissymmetrically core-extended naphthalene diimides derived from o-phenylenediamine and cyanoethene dithiolate were explored. The push-pull nature of the peripheral substituents allows these naphthalene diimide dyes and their progenitors to display interesting photophysical and electrochemical properties, with the target system acting as a highly reversible and quantitative molecular switch with clear absorption and emission readouts based on chemical oxidation and reduction processes.
Subject Organic Chemical Synthesis
Sensory Systems
Keyword(s) Dyes
Fluorescence
Naphthalene diimides
Push-pull system
Redox switch
DOI - identifier 10.1002/ajoc.201402015
Copyright notice © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
ISSN 2193-5807
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